图 书 馆
小分子光谱与动力学Small-Molecule Spectroscopy and Dynamics |
|
| 课程网址: | https://ocw.mit.edu/courses/chemistry/5-80-small-molecule-spectro... |
| 主讲教师: | Prof. Robert Field |
| 开课单位: | 麻省理工学院 |
| 开课时间: | 2008-10-01 |
| 课程语种: | 英语 |
| 中文简介: |  |
| 课程简介: | The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy. |
| 关 键 词: | 小分子光谱; 动力学; 哈密顿模型 |
| 课程来源: | 麻省理工学院公开课 |
| 数据采集: | 2021-09-23：nkq |
| 最后编审: | 2021-09-25：nkq |
| 阅读次数: | 53 |