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碱改性过渡金属催化剂上丙烯的选择性催化氧化

Selective catalytic oxidation of propene over alkali modified transition metal catalysts
课程网址: http://videolectures.net/forum40_terzan_selective_catalytic_oxida...  
主讲教师: Janvit Teržan
开课单位: 卢布尔雅那化学研究所
开课时间: 2019-07-01
课程语种: 英语
中文简介:
环氧丙烷是一种极其重要的工业构件。主要用于聚氨酯塑料的生产。目前的生产方法要么昂贵,要么对环境征税。使用分子氧直接气相丙烯氧化可以解决大多数问题。然而,这些工艺也存在一些缺点,即选择性低和催化剂失活。我们设计的催化剂结构相似,在丙烯环氧化反应中表现出非常不同的选择性。利用这些材料,我们进行了一些原位和操作数分析,并将它们与理论方法相结合。目的是识别丙烯环氧化反应中观察到的选择性差异的潜在原因。
课程简介: Propylene oxide is an immensely important industrial building block. It is mostly used in production of polyurethane plastics. Current production methods are either expensive of environmentally taxing. Direct gas phase propylene oxidation using molecular oxygen would solve most of these problems. However, these processes also suffer from several drawbacks, namely low selectivity and catalyst deactivation. We designed catalysts that were similar in structure and showed very different selectivity in the propylene epoxidation. With these materials we performed several in situ and operando analysis and combined them with theoretical methods. The goal was to discern the underlying reasons for the observed differences in selectivity during propylene epoxidation reaction.
关 键 词: 环氧丙烷; 聚氨酯塑料; 丙烯环氧化反应
课程来源: 视频讲座网
数据采集: 2021-11-19:zkj
最后编审: 2021-11-19:zkj
阅读次数: 46