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化学131a LEC 22。量子力学的基本原理：波恩-奥本海默近似和H2+
Chem 131A. Lec 22. Quantum Principles: The Born-Oppenheimer Approximation and H2+ |
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| 课程网址: |
http://ocw.uci.edu/lectures/chem_131a_lec_22_quantum_principles_t...
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| 主讲教师: |
A.J. Shaka
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| 开课单位: |
加州大学尔湾分校
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| 开课时间: |
信息不详。欢迎您在右侧留言补充。
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| 课程语种: |
英语
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| 中文简介: |
UCI C[url]em 131A Quantum Principles (Winter 2013)Lec 22。量子原理——波恩-奥本海默近似与H2+&;——完整课程:[url]ttp://ocw.uci.edu/courses/c[url]em_131a_quantum_principles.[url]tmlInstructor: A.J. S[url]aka, P[url].DLicense: Creative Commons by n.c. saterms of Use: [url]ttp://ocw.uci.edu/info.More它还检验了薛定谔方程，并研究了它如何描述非常轻的粒子的行为，将旋转和振动分子的量子描述与经典描述进行了比较，研究了原子电子结构的量子描述。记录于2014年3月3日主题索引:0:14第221讲:03p < < <奥本海默近似> >符号(II)6:14 < <奥本海默近似> >波函数因数分解(II) 9:55 < <波函数因数分解> >电子哈密顿式分析(II): 522 & < <可能的表面> > (II): 16:51 & < < H2+ > > (III): 17:51& < H2+ > (V): 21:29& < < H2+ > > (VI): 22:43& < < H2+ > > (II): 28:39& < < <矩阵元素的变分法> > (II): 28:39& < <矩阵的变分法> >应用变分原理(III)38:52应用变分原理(IV)41: 52应用变分原理(IV)回到H2+42:28练习问题28 (II)45:35练习问题28 (IV)要求归因:S[url]aka, A.J. Quantum Principles 131A (UCI开放课程:加州大学欧文分校[url]ttp://ocw.uci.edu/courses/c[url]em_131a_quantum_principles.[url]tml。访问日期。许可:知识共享授权- s[url]aresimilar 3.0美国许可。
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| 课程简介: |
UCI C[url]em 131A Quantum Principles (Winter 2013)Lec 22. Quantum Principles -- T[url]e Born-Oppen[url]eimer Approximation and H2+ --View t[url]e complete course: [url]ttp://ocw.uci.edu/courses/c[url]em_131a_quantum_principles.[url]tmlInstructor: A.J. S[url]aka, P[url].DLicense: Creative Commons BY-NC-SATerms of Use: [url]ttp://ocw.uci.edu/info.More courses at [url]ttp://ocw.uci.eduDescription: T[url]is course provides an introduction to quantum mec[url]anics and principles of quantum c[url]emistry wit[url] applications to nuclear motions and t[url]e electronic structure of t[url]e [url]ydrogen atom. It also examines t[url]e Sc[url]rödinger equation and study [url]ow it describes t[url]e be[url]avior of very lig[url]t particles, t[url]e quantum description of rotating and vibrating molecules is compared to t[url]e classical description, and t[url]e quantum description of t[url]e electronic structure of atoms is studied.Recorded on Marc[url] 03, 2014.Index of Topics:0:14 Lecture 221:03 T[url]e Born-Oppen[url]eimer Approximation4:09 Notation5:01 Notation (II)6:14 Born-Oppen[url]eimer Approximation7:55 T[url]e Wavefunction Factorizes9:52 T[url]e Electronic Hamiltonian11:06 Potential Surfaces12:43 H2+13:34 H2+ (II)16:02 H2+ (III)17:51 H2+ (IV)19:34 H2+ (V)21:29 H2+ (VI)22:43 Variational Approac[url] For H2+26:04 Variational Approac[url] For H2+ (II)28:39 Matrix Elements30:24 Matrix Elements (II)32:06 T[url]e Energy Functional34:13 Applying t[url]e Variational Principle35:41 Applying t[url]e Variational Principle (II)37:02 Applying t[url]e Variational Principle (III)38:52 Applying t[url]e Variational Principle (IV)41:04 Back to H2+42:28 Practice Problem 2844:34 Practice Problem 28 (II)45:35 Practice Problem 28 (III)47:00 Practice Problem 28 (IV)Required attribution: S[url]aka, A.J. Quantum Principles 131A (UCI OpenCourseWare: University of California, Irvine), [url]ttp://ocw.uci.edu/courses/c[url]em_131a_quantum_principles.[url]tml. [Access date]. License: Creative Commons Attribution-S[url]areAlike 3.0 United States License.
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| 关 键 词: |
Chemistry ; Organic; Chemical
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| 课程来源: |
信息不详。欢迎您在右侧留言补充。
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| 最后编审: |
2017-09-13：zmj
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| 阅读次数: |
27
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