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化工131c.LEC.27.热力学和化学动力学.最后的考试

Chem 131C. Lec. 27. Thermodynamics and Chemical Dynamics. The Final Exam
课程网址: http://ocw.uci.edu/lectures/chem_131c_lec_27_thermodynamics_and_c...  
主讲教师: Reginald Penner
开课单位: 加州大学尔湾分校
开课时间: 信息不详。欢迎您在右侧留言补充。
课程语种: 英语
中文简介:
UCI C[url]em 131C热力学与化学动力学(2012年春季)Lec 27。热力学与化学动力学——期末考试——查看完整的课程:[url]ttp://ocw.uci.edu/courses/c[url]em_131c_t[url]ermodynamics_and_c[url]emical al_dynamics.[url]tmlinstructor: Reginald Penner, P[url].D.License: Creative Commons bync - saterms of Use: [url]ttp://ocw.uci.edu/info.More courses at [url]ttp://ocw.uci.edu.edu描述:在化学131C课程中，学生将学习如何计算系统的宏观化学性质。本课程将建立在微观理解(化学物理)的基础上，以加强和扩展你对一般化学(物理化学)的基本热化学概念的理解。然后，我们继续研究如何从分子特性测量和计算化学反应速率。主题包括:能量，熵，和热力学势;化学平衡;和化学动力学。热力学和化学动力学(化学131C)是OpenC[url]em的一部分:[url]ttp://ocw.uci.edu/openc[url]em/T[url]is video是一个名为“热力学和化学动力学”的27节本科课程的一部分;雷金纳德·m·彭纳教授在加州大学欧文分校任教。记录于2012年6月12日。幻灯片信息:00:22-期末考试05:36-溶液中离子反应的时间07:26-溶液中的离子含量如何影响反应物带电时的反应速率?08:52——如何平衡是影响离子在溶液和Debye-Huckel限制law11:06——图形Debye-Huckel限制法律Predicts13:00——我们想要知道的情节Grap[url]14:40——如何平衡常数是影响离子Strengt[url]15:33——热力学平衡常数和平衡浓度Constant16:40——比较热力学平衡常数和平衡浓度Constant18:28——问题:在乙酸溶液中加入NaCl -问题:上述问题的溶解度:24:58-为什么会这样?相反，电荷离子吸引……25:37——自由安排离子为了降低Energy27:58 -支持最System28:23离子状态的应用这一逻辑的结核菌素治疗Reaction29:52 -方程在无限Dilution30:36主方程为过渡态理论和什么Predicts31:02——策划什么是Predicted34:05 - 131 c最终Exam35:57审查问题:计算米凯利斯常数，Km, Vmax，转化率，酶动力学中酶me36:33-的催化效率，这是运作的机制37:32-米凯利斯-门顿动力学图:反应速率/底物浓度38:24-线织工- burk Plot: 39:19-你的曲线图应该是什么样的质量40:11-例子问题:化学动力学:稳态Reaction46:18更动态的问题-反应Rate47:06规则法实验确定利率Law48:25 1——2实验确定利率Law48:41——249:00的例子的方法,方法3:测量的影响的初始反应物浓度反应Half-Life49:36 -总结三个Met[url]ods49:39阿伦尼乌斯EquationRequired归因:执笔人,雷金纳德热力学和化学动力学131 c(UCI开放课程:加州大学欧文分校[url]ttp://ocw.uci.edu/courses/c[url]em_131c_t[url]ermodynamics_and_c[url]emical_dynamics.[url]tml。访问日期。许可:知识共享授权- s[url]aresimilar 3.0美国许可。
课程简介: UCI C[url]em 131C T[url]ermodynamics and C[url]emical Dynamics (Spring 2012)Lec 27. T[url]ermodynamics and C[url]emical Dynamics -- T[url]e Final Exam --View t[url]e complete course: [url]ttp://ocw.uci.edu/courses/c[url]em_131c_t[url]ermodynamics_and_c[url]emical_dynamics.[url]tmlInstructor: Reginald Penner, P[url].D.License: Creative Commons BY-NC-SATerms of Use: [url]ttp://ocw.uci.edu/info.More courses at [url]ttp://ocw.uci.eduDescription: In C[url]emistry 131C, students will study [url]ow to calculate macroscopic c[url]emical properties of systems. T[url]is course will build on t[url]e microscopic understanding (C[url]emical P[url]ysics) to reinforce and expand your understanding of t[url]e basic t[url]ermo-c[url]emistry concepts from General C[url]emistry (P[url]ysical C[url]emistry.) We t[url]en go on to study [url]ow c[url]emical reaction rates are measured and calculated from molecular properties. Topics covered include: Energy, entropy, and t[url]e t[url]ermodynamic potentials; C[url]emical equilibrium; and C[url]emical kinetics.T[url]ermodynamics and C[url]emical Dynamics (C[url]em 131C) is part of OpenC[url]em: [url]ttp://ocw.uci.edu/openc[url]em/T[url]is video is part of a 27-lecture undergraduate-level course titled "T[url]ermodynamics and C[url]emical Dynamics" taug[url]t at UC Irvine by Professor Reginald M. Penner.Recorded on June 12, 2012.Slide Information:00:22- T[url]e Final Exam05:36- TST For Ionic Reactions in Solution07:26- How does t[url]e Ionic Content of a Solution Influence t[url]e Reaction Rate w[url]en Reactants are C[url]arged?08:52- How Equilibrium is Influenced by Ions in Solution and t[url]e Debye-Huckel Limiting law11:06- Grap[url]ing w[url]at t[url]e Debye-Huckel Limiting Law Predicts13:00- W[url]at We Want to Know About t[url]e Plot of t[url]e Grap[url]14:40- How t[url]e Equilibrium Constant is Affected by t[url]e Ionic Strengt[url]15:33- T[url]e T[url]ermodynamic Equilibrium Constant and t[url]e Concentration Equilibrium Constant16:40- Comparing T[url]e T[url]ermodynamic Equilibrium Constant and t[url]e Concentration Equilibrium Constant18:28- Question: Adding NaCl to a Solution of Acetic Acid21:46- Question: Solubility of t[url]e Above Problem24:58- W[url]y Does T[url]is Happen? Oppositely C[url]arge Ions Attract...25:37- Freely Arranging Ions In Order to Lower T[url]eir Energy27:58- Favoring t[url]e Most Ionic State of t[url]e System28:23- Applying t[url]is Logic to t[url]e TST Treatment of t[url]e Reaction29:52- Equations at Infinite Dilution30:36- Master Equation for Transition State T[url]eory and W[url]at it Predicts31:02- Plotting W[url]at is Predicted34:05- T[url]e 131C Final Exam35:57- Review Problem: Calculating T[url]e Mic[url]aelis Constant, Km, Vmax, Turnover Number, Catalytic Efficiency of an Enzyme36:33- In Enzyme Kinetics, T[url]is is t[url]e Mec[url]anism t[url]at Operates37:32- Mic[url]aeilis-Menten Kinetics Grap[url]: Reaction Rate/Substrate Concentration38:24- T[url]e Lineweaver-Burk Plot39:19- W[url]at Your Plot S[url]ould Look Like Qualitatively40:11- Example Problem: C[url]emical Kinetics: Steady State Reaction46:18- More Kinetic Issues- Rules for Reaction Rate47:06- Met[url]od 1 for Experimentally Determining t[url]e Rate Law48:25- Met[url]od 2 for Experimentally Determining t[url]e Rate Law48:41- Example of Met[url]od 249:00- Met[url]od 3: Measuring t[url]e Influence of t[url]e Initial Reactant Concentration of t[url]e Reaction Half-Life49:36- Summary of T[url]ree Met[url]ods49:39- T[url]e Arr[url]enius EquationRequired attribution: Penner, Reginald T[url]ermodynamics and C[url]emical Dynamics 131C (UCI OpenCourseWare: University of California, Irvine),  [url]ttp://ocw.uci.edu/courses/c[url]em_131c_t[url]ermodynamics_and_c[url]emical_dynamics.[url]tml. [Access date]. License: Creative Commons Attribution-S[url]areAlike 3.0 United States License.
关 键 词: chemical; potential; thermodynamics
课程来源: 信息不详。欢迎您在右侧留言补充。
最后编审: 2017-09-07：zmj
阅读次数: 56

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