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用电子陷阱的能量分辨密度识别金属氧化物粉末的新概念

A Novel Concept of Identification of Metal-oxide Powders by Energy-resolved Density of Electron Traps
课程网址: https://videolectures.net/preglov_ohtani_metal_oxide_powders/  
主讲教师: Bunsho Ohtani
开课单位: Preglov kolokvij会议
开课时间: 2017-08-22
课程语种: 英语
中文简介:
通过最新开发的反向双束光声光谱(RDB-PAS)评估了金属氧化物颗粒中电子陷阱(ERDT)和导带底部(CBB)的能量分辨分布作为价带顶部能量的函数,其中通过使用625nm的调制LED光的光声光谱法(PAS)测量了由VB直接激发的ET中电子的光吸收。在本研究中,讨论了如何使用ERDT/CBB图案作为指纹,通过加权一致度乘以ERDT图案的一致度、ET和CBB的总密度,以及ERDT/CSB图案的一致程度与光催化活性之间的相关性,来识别具有带隙的金属氧化物(二氧化钛、铌等)颗粒和ET。
课程简介: Energy-resolved distribution of electron traps (ERDT) as well as conduction-band bottom (CBB) in metal oxide particles as a function of energy from valence-band (VB) top has been evaluated by newly developed reversed double-beam photoacoustic spectroscopy (RDB-PAS), in which photoabsorption of electrons in ETs directly excited from VB by irradiation of intense continuous light is measured by photoacoustic spectroscopy (PAS) using modulated LED light at 625 nm. In this study, how to use ERDT/CBB patterns as a finger print for identification of metal oxide (titania, niobia and the others) particles having band gap and ETs by weighted degree of coincidence multiplied by the degrees of coincidence of ERDT patterns, total density of ETs and CBB, and correlation between degree of coincidences of ERDT/CBB patterns and photocatalytic activities are discussed.
关 键 词: 电子陷阱; 密度识别; 金属氧化物; 新概念
课程来源: 视频讲座网
数据采集: 2024-04-25:liyq
最后编审: 2024-04-25:liyq
阅读次数: 11