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润湿和微米大小的椭圆接触线

Wetting and Contact Lines of Micrometer-sized Ellipsoids
课程网址: http://videolectures.net/kolokviji_christophe_wac/  
主讲教师: Jean Christophe Loudet
开课单位: 里歇尔中心
开课时间: 2007-12-22
课程语种: 英语
中文简介:
本文从实验和理论上研究了固体微米大小的椭球粒子对流体界面的润湿作用。后者由单分散聚苯乙烯球(半径r=5μm)的单轴拉伸获得,并且纵横比k在1到10之间变化。我们已经证明,这种油水界面的椭球体表现出相当大能量的长程毛细管相互作用,高达热能的105倍。接触线呈现鞍状变形,具有四极对称性:界面在椭球体的尖端附近被拉下,在粒子中心附近被拉起。两个椭球体互相吸引尖端或并排吸引,但在侧面到尖端配置中相互排斥。这些趋势确实符合一般规律,即同一符号的毛细电荷之间的相互作用具有吸引力,而相反符号的电荷之间的相互排斥。为了解释我们的实验数据,我们用数值方法解决了单个椭球体上的局部湿润问题,发现接触线实际上是一条具有四极对称性的鞍形曲线。此外,实验数据和模拟数据的比较使我们能够确定接触角,更出人意料的是,后者随着椭球长宽比的增加而显著降低。
课程简介: We experimentally and theoretically investigated the wetting of a fluid interface on solid micrometer-sized ellipsoidal particles. The latter were obtained from uniaxial stretching of monodisperse polystyrene spheres (radius R = 5m) and the aspect ratio, k, was varied from 1 to about 10. We have demonstrated that such ellipsoids at oil-water interfaces manifest long range capillary interactions of considerable energies, up to about 105 times the thermal energy. The contact line exhibits saddle-like deformations and has a quadrupolar symmetry: the interface is pulled down near the tips of the ellipsoid and pulled up near the middle of the particle. Two ellipsoids attract each other tip to tip or side by side but repel one another when in a side-to-tip configuration. These trends are indeed in line with the general rule according to which the interaction between capillary charges of the same sign is attractive while it is repulsive between charges of opposite signs. To interpret our experimental data, we numerically solved the partial wetting problem on a single ellipsoid and found that the contact line is indeed a saddle-shaped curve with a quadrupolar symmetry. Furthermore, comparisons of experimental and simulated data allowed us to determine contact angles and rather unexpectedly, the latter were found to decrease significantly with increasing ellipsoid aspect ratio.
关 键 词: 微米尺寸; 接触线; 毛细管电荷; 马鞍形曲线
课程来源: 视频讲座网
最后编审: 2020-01-07:lxf
阅读次数: 64