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5.80 小分子光谱学与动力学5.80 Small-Molecule Spectroscopy and Dynamics |
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| 课程网址: | http://ocw.mit.edu/courses/chemistry/5-80-small-molecule-spectros... |
| 主讲教师: | Robert Field |
| 开课单位: | 麻省理工学院 |
| 开课时间: | 信息不详。欢迎您在右侧留言补充。 |
| 课程语种: | 英语 |
| 中文简介: |  |
| 课程简介: | The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy. |
| 关 键 词: | 光谱学; 谐波振荡器; 矩阵; 哈密顿量; 海森堡; 振动转子; 硅藻土; 激光方案; 角动量; 能级; 二阶效应; 扰动; 刚性 |
| 课程来源: | 麻省理工学院公开课 |
| 最后编审: | 2018-05-26：cmh |
| 阅读次数: | 34 |