图 书 馆
讲课11：分子的形状，电子域理论，二次键Lecture11: The Shapes of Molecules, Electron Domain Theory, Secondary Bonding |
|
| 课程网址: | http://videolectures.net/mit3091f04_sadoway_lec11/ |
| 主讲教师: | Donald R. Sadoway |
| 开课单位: | 麻省理工学院 |
| 开课时间: | 2009-02-10 |
| 课程语种: | 英语 |
| 中文简介: |  |
| 课程简介: | //"And to go beyond that really requires some intensive quantum mechanics. So, we're going to stay with s and p-block. And we saw that if we had two atomic s-orbitals, when they blended to form the molecular orbital, it took on this sort of the ellipsoidal shape.// //We called that a sigma orbital. And, the characteristic of the sigma orbital is that you have continuous electron density from one nucleus to the other. We said no holidays; constant electronic density.// //We could then combine an s orbital and a p orbital, as for example in the case of hydrogen fluoride. In the case of s plus p, will end up with an orbital that looks something like this. And, it is also termed a sigma orbital because, again, if you look from one nucleus to the other, there is continuous electron density, no holidays...."// |
| 关 键 词: | 量子力学; 分子轨道; 电子密度 |
| 课程来源: | 视频讲座网 |
| 最后编审: | 2019-05-19：lxf |
| 阅读次数: | 41 |