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红外光谱法鉴定博物馆馆藏中的塑料材料

Identification of Plastic Materials in Museum Collections with Infrared Spectroscopy
课程网址: http://videolectures.net/MAOplastika2017_padovnik_plastic_materia...  
主讲教师: Andreja Padovnik
开课单位: 斯洛文尼亚文化遗产保护研究所
开课时间: 2017-04-20
课程语种: 英语
中文简介:
塑料制品是聚合物基材料,正在成为文化遗产的组成部分,特别是在建筑和设计博物馆收藏中。通常,这些聚合物的研究较少,其化学分解尚未得到充分阐明。 聚合物这个词来源于希腊语poly和meros,分别表示许多和部分。识别塑料类型通常具有挑战性,因为塑料可用于多种配方,其中基础聚合物与有机和无机添加剂混合。为了建立适当的条件来储存和保存塑料物体,有必要了解它们的成分,因为它们对各种环境影响(空气,水分,光,热)的敏感性。因此,识别塑料成分是保存和保存塑料物体的第一步。 研究集中在来自不同时期的十四个塑料物体上:电话ISKRA ATA 12,钻孔机EVS,灯洛丽塔,布里翁维加收音机,电话Iskra ETA 80,儿童玩具船,日历,儿童拨浪鼓,衣架,架子卡特尔,Kogoj的儿童餐具, 鳞片塞萨尔,废物篮SJM扎巴和椅子梅布洛。 在该分析中,使用金刚石ATR晶体(ATR-FTIR)的傅里叶变换红外光谱用于鉴定聚合物。ATR-FTIR光谱被证明是表征遗产收藏中聚合物材料的合适方法。 鉴定了以下聚合物:电木、天然橡胶、聚苯乙烯、聚氯乙烯、聚甲醛、聚酯树脂、丁苯橡胶、苯乙烯丙烯腈、丙烯腈-丁二烯-苯乙烯、聚乙烯、聚丙烯(PP)、聚酰胺(PA)。
课程简介: Plastic objects are polymer-based materials and are becoming integral parts of cultural heritage, especially in architecture and design museum collections. Often these polymers are less well studied and their chemical decomposition has not yet been fully elucidated. The word polymer is derived from the Greek words poly and meros, meaning many and parts, respectively. Identifying the type of plastic is often challenging because plastics are available in a wide range of formulations where base polymers are mixed with organic and inorganic additives. To set up the proper conditions for the storage and conservation of plastic objects it is necessary to understand their composition because of their susceptibility to various environmental impacts (air, moisture, light, heat). The identification of the composition of plastics is therefore the first step in the preservation and conservation of plastic objects. The research focused on fourteen plastic objects from different time periods: the telephone ISKRA ATA 12, the drilling machine EVS, the lamp Lolita, the radio Brionvega, the telephone Iskra ETA 80, a children’s toy boat, a calendar, a children's rattle, a coat hanger, the shelf Kartell, the children's cutlery by Kogoj, the scales Cesar, the waste basket SJM Žaba and the chair Meblo. In this analysis Fourier transform infrared spectroscopy with a diamond ATR crystal (ATR-FTIR) was used for the identification of polymers. ATR-FTIR spectroscopy was shown to be a suitable method for the characterization of polymer materials from heritage collections. The following polymers were identified: Bakelite, natural rubber (NR), polystyrene (PS), polyvinyl chloride (PVC), polyformaldehyde (POM), polyester resin, styrene butadiene rubber (SBR), styrene acrylonitrile (SAN), acrylonitrile-butadiene-styrene (ABS), polyethylene (PE), polypropylene (PP), polyamide (PA).
关 键 词: 塑料物品; 文化遗产; 聚合物
课程来源: 视频讲座网
数据采集: 2020-11-19:cjy
最后编审: 2020-11-19:cjy
阅读次数: 40