首页无机化学
   首页化学
   首页自然科学
0


用电子陷阱能量分辨密度识别金属氧化物粉末的新概念

A Novel Concept of Identification of Metal-oxide Powders by Energy-resolved Density of Electron Traps
课程网址: http://videolectures.net/preglov_ohtani_metal_oxide_powders/  
主讲教师: Bunsho Ohtani
开课单位: 北海道大学
开课时间: 2017-08-22
课程语种: 英语
中文简介:
利用新近发展起来的反向双光束光声光谱(RDB-PAS)研究了金属氧化物颗粒中电子陷阱(ERDT)和导带底(CBB)的能量分辨分布随价带顶部能量的变化,用625nm调制的LED光,用光声光谱(PAS)测量了VB直接激发的电子在625nm处的光吸收。在本研究中,如何使用ERDT/CBB图形作为指纹识别具有带隙和ETs的金属氧化物(二氧化钛、铌酸锂等)粒子,通过加权重合度乘以ERDT图案的重合度、ETs和CBB的总密度,讨论了ERDT/CBB图形的重合度与光催化活性的关系。
课程简介: Energy-resolved distribution of electron traps (ERDT) as well as conduction-band bottom (CBB) in metal oxide particles as a function of energy from valence-band (VB) top has been evaluated by newly developed reversed double-beam photoacoustic spectroscopy (RDB-PAS), in which photoabsorption of electrons in ETs directly excited from VB by irradiation of intense continuous light is measured by photoacoustic spectroscopy (PAS) using modulated LED light at 625 nm. In this study, how to use ERDT/CBB patterns as a finger print for identification of metal oxide (titania, niobia and the others) particles having band gap and ETs by weighted degree of coincidence multiplied by the degrees of coincidence of ERDT patterns, total density of ETs and CBB, and correlation between degree of coincidences of ERDT/CBB patterns and photocatalytic activities are discussed.
关 键 词: 电子陷阱能量; 密度识别; 金属氧化物
课程来源: 视频讲座网
数据采集: 2020-11-29:yxd
最后编审: 2021-09-20:zyk
阅读次数: 80