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第15课-化学反应性：SOMO、HOMO和LUMOLecture 15 - Chemical Reactivity: SOMO, HOMO, and LUMO |
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| 课程网址: | http://videolectures.net/yalechem125f08_mcbride_lec15/ |
| 主讲教师: | J. Michael McBride |
| 开课单位: | 耶鲁大学 |
| 开课时间: | 2010-06-09 |
| 课程语种: | 英语 |
| 中文简介: |  |
| 课程简介: | Professor McBride begins by using previous examples of "pathological" bonding and the BH3 molecule to illustrate how a chemist's use of localized bonds, vacant atomic orbitals, and unshared pairs to understand molecules compares with views based on the molecule's own total electron density or on computational molecular orbitals. This lecture then focuses on understanding reactivity in terms of the overlap of singly-occupied molecular orbitals (SOMOs) and, more commonly, of an unusually high-energy highest occupied molecular orbital (HOMO) with an unusually low-energy lowest unoccupied molecular orbital (LUMO). This is shown to be a generalization of the traditional concepts of acid and base. Criteria for assessing reactivity are outlined and illustrated. |
| 关 键 词: | 单占据分子轨道; 异常高能最高占据分子轨道; 常低能最低未占据分子轨道 |
| 课程来源: | 视频讲座网 |
| 数据采集: | 2021-11-17：zkj |
| 最后编审: | 2021-12-20：liyy |
| 阅读次数: | 805 |