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新型二氧化钛纳米管光(电)催化反应器的设计与开发

Design and development of novel titania nanotubes based photo(electro)catalytic reactor
课程网址: http://videolectures.net/ipssc2017_suhadolnik_titania_nanotubes/  
主讲教师: Luka Suhadolnik
开课单位: 约瑟夫·斯特凡研究所
开课时间: 2017-05-23
课程语种: 英语
中文简介:
基于光电催化技术,设计并组装了一种新型高效的水和空气净化光(电)催化反应器,可在不使用任何有害氧化剂的情况下完全降解有机污染物。反应器的活性部分由纳米二氧化钛组成,二氧化钛被紫外光照射,从而产生电子和空穴,参与半导体表面的氧化和还原反应。由于二氧化钛纳米管薄膜是通过阳极氧化过程生长的,因此它牢固地附着在不同形式和形状的金属钛上,并且在处理过程中不会被冲走。在我们的工作中,我们研究了阳极氧化和退火过程中最重要的参数,这些参数决定了多晶TiO2纳米管的形态、长度和晶体结构。我们发现二氧化钛纳米管的最佳长度在15到20µm之间,这使得能够有效捕获入射紫外线照射并控制电子-空穴复合时间。通过对咖啡因和苯酚的降解研究,测量了这样处理的活性光催化部件的效率。这些活性光催化阳极随后被组装到一个大容量反应器(1.5升)中,并以这种方式放置在金属阴极和紫外光源旁边,以实现光催化剂的均匀照明。目前,该大容量反应器已被测试可降解纺织、制药和造纸工业实际废水中的有机化合物。
课程简介: A new highly-efficient photo(electro)catalytic reactor for water and air purification was designed and assembled based on photoelectrocatalytic technology to completely degrade organic pollutants without any hazardous oxidants. The active part of the reactor consists of nanosized titanium dioxide, which is illuminated with UV light, hence generating electrons and holes that take part in the oxidation and reduction reactions at the semiconductor’s surface. Since titania nanotubes film is grown by anodic oxidation process it is consequently firmly attached to different forms and shapes of metal titanium and cannot be washed away during the treatment. In our work we studied the most important parameters of anodic oxidation and annealing procedure that determine the morphology, length, and crystal structure of polycrystalline TiO2 nanotubes. We found out that the optimum length of titania nanotubes is between 15 to 20 µm which enables effective capture of the incident UV illumination and control of electron-hole recombination time. The efficiency of thus processed active photocatalytic parts was measured via degradation studies of caffeine and phenol. These active photocatalytic anodes were later assembled into a large-volume reactor (1.5 l) and positioned next to metal cathodes and UV light sources in such a way to achieve a uniform illumination of the photocatalyst. Currently, this large-volume reactor is tested to degrade organic compounds present in real waste waters from textile, pharmaceutical and paper production industries.
关 键 词: 光电催化技术; 催化反应器; 纳米二氧化钛
课程来源: 视频讲座网
数据采集: 2021-11-26:zkj
最后编审: 2021-11-26:zkj
阅读次数: 46