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粘弹性相分离和机械断裂之间的共同性

Commonality between viscoelastic phase separation and mechanical fracture
课程网址: http://videolectures.net/fmf_tanaka_fracture/  
主讲教师: Hajime Tanaka
开课单位: 东京大学
开课时间: 2012-08-08
课程语种: 英语
中文简介:
相分离是在材料和自然界中产生空间不均匀图案的最基本现象之一。到目前为止,它已分为三种类型:(i)固体,(ii)流体,和(iii)粘弹性相分离。在这里,我们报告了伴随裂缝的另一种相分离行为,其在聚合物溶液中在足够深的淬火下观察到。令人惊讶的是,断裂成为相分离的主要粗化过程。在深度淬火下,通过聚合物之间强烈吸引的相互作用形成瞬态凝胶。聚合物网络的连通性对抗相分离并产生内部应力场。当该应力场超过瞬态凝胶的机械稳定性极限时,发生机械断裂:断裂相分离。粘弹性和断裂相分离的行为源于成分和变形场之间的强耦合。我们证明密度和变形场之间的相同类型的耦合导致在剪切下的流体空化和玻璃状液体和变形下的固体的机械破裂。关键的共同概念是“动态不对称”。我们讨论了这些明显不相关现象的共同物理学以及模式演化的动力学路径的选择原则。例如,相分离和断裂之间的唯一区别可能源于变形是通过相分离本身还是通过加载从外部产生的。
课程简介: Phase separation is one of the most fundamental phenomena that create spatially inhomogeneous patterns in materials and nature. It has so far been classified into three types: (i) solid, (ii) fluid, and (iii) viscoelastic phase separation. Here we report another phase-separation behaviour accompanying fracture, which is observed under a sufficiently deep quench in polymer solutions. Surprisingly, fracture becomes a dominant coarsening process of the phase separation. Under a deep quench, a transient gel is formed by strong attractive interactions between polymers. The connectivity of the polymer network acts against phase separation and produces the internal stress field. When this stress field exceeds the mechanical stability limit of the transient gel, mechanical fracture takes place: fracture phase separation. The behaviour of viscoelastic and fracture phase separation originates from a strong coupling between composition and deformation field. We demonstrate that the same type of coupling between density and deformation field leads to cavitation of fluid under shear and mechanical fracture of glassy liquid and solid under deformation. The key common concept is "dynamic asymmetry". We discuss a common physics underlying these apparently unrelated phenomena and a selection principle of the kinetic pathway of pattern evolution. For example, the only difference between phase separation and fracture may stem from whether deformation is produced internally by phase separation itself or externally by loading.
关 键 词: 粘弹性相分离; 聚合物; 机械骨折
课程来源: 视频讲座网
最后编审: 2020-06-27:zyk
阅读次数: 37