图 书 馆
提供机制和性能见解的高级光谱学Observing dynamics processes in energy materials - Advanced spectroscopy providing insights in mechanisms and performance |
|
| 课程网址: | https://videolectures.net/preglov_tromp_observing/ |
| 主讲教师: | Moniek Tromp |
| 开课单位: | Preglov kolokvij会议 |
| 开课时间: | 2020-03-02 |
| 课程语种: | 英语 |
| 中文简介: |  |
| 课程简介: | An important element in the reduction of CO2 is the change of vehicles with internal combustion engines to electric battery powered vehicles. The as such produced renewable energy can be used for individual mobility as well as for a temporary intermediate storage of excess energy. A viable electric mobility concept requires however stable cycle batteries with high specific energy (minimising weight, maximising driving range). Li ion batteries are widely used in applications such as mobile phones and laptops, and will likely be key to future electromobility. Alternative promising battery are lithium sulphur, metallic lithium and full solid state batteries with significantly higher capacities, or more sustainable batteries based on iron. The requirements for such batteries present major challenges; e.g. energy capacity, deactivation/stability and safety. A detailed understanding of the charge, discharge and deactivation mechanisms are thus required, preferably quantitative and spatially resolved. X-ray absorption spectroscopy (XAS) is a characterisation technique which provides detailed electronic and structural information on the material under investigation, in a time- and spatially resolved manner. Here, I will explain the strengths and limitations of XAS for battery research. A novel operando XAS cell design will be described, including the challenges to perform reliable experiments (electrochemically and spectroscopically). The cell allows time and spatial resolved XAS, providing insights in the type, location and reversibility of the intermediates formed in electrodes and electrolyte separately. Obtained insights in cycling and deactiviation mechanisms for the different battery types will be discussed and other energy materials like fuel cells as well as future research directions described. |
| 关 键 词: | 能源材料; 动力学; 高级光谱学 |
| 课程来源: | 视频讲座网 |
| 数据采集: | 2024-04-25：liyq |
| 最后编审: | 2024-04-25：liyq |
| 阅读次数: | 14 |