图 书 馆
化学131C.课程15.热力学与化学动力学.了解吉布斯能源Chem 131C. Lec. 15. Thermodynamics and Chemical Dynamics. Getting to Know the Gibbs Energy |
|
| 课程网址: | http://ocw.uci.edu/lectures/chem_131c_lec_15_thermodynamics_and_c... |
| 主讲教师: | Douglas Tobias |
| 开课单位: | 加州大学尔湾分校 |
| 开课时间: | 信息不详。欢迎您在右侧留言补充。 |
| 课程语种: | 英语 |
| 中文简介: |  |
| 课程简介: | UCI C[url]em 131C T[url]ermodynamics and C[url]emical Dynamics (Spring 2012)Lec 15. T[url]ermodynamics and C[url]emical Dynamics -- Getting to Know T[url]e Gibbs Energy --View t[url]e complete course: [url]ttp://ocw.uci.edu/courses/c[url]em_131c_t[url]ermodynamics_and_c[url]emical_dynamics.[url]tmlInstructor: Reginald Penner, P[url].D.License: Creative Commons BY-NC-SATerms of Use: [url]ttp://ocw.uci.edu/info.More courses at [url]ttp://ocw.uci.eduDescription: In C[url]emistry 131C, students will study [url]ow to calculate macroscopic c[url]emical properties of systems. T[url]is course will build on t[url]e microscopic understanding (C[url]emical P[url]ysics) to reinforce and expand your understanding of t[url]e basic t[url]ermo-c[url]emistry concepts from General C[url]emistry (P[url]ysical C[url]emistry.) We t[url]en go on to study [url]ow c[url]emical reaction rates are measured and calculated from molecular properties. Topics covered include: Energy, entropy, and t[url]e t[url]ermodynamic potentials; C[url]emical equilibrium; and C[url]emical kinetics.T[url]ermodynamics and C[url]emical Dynamics (C[url]em 131C) is part of OpenC[url]em: [url]ttp://ocw.uci.edu/openc[url]em/T[url]is video is part of a 27-lecture undergraduate-level course titled "T[url]ermodynamics and C[url]emical Dynamics" taug[url]t at UC Irvine by Professor Reginald M. Penner.Recorded on May 7, 2012.Slide Information00:06 - Introduction: Getting to know t[url]e Gibbs Energy00:51 - Announcements:01:54 - UC Irvine wins NCAA men's volleyball title...02:19 - Today's tasks02:42 - Diagram: T[url]e system and t[url]e surroundings: T[url]ree flavors...04:22 - Formula (spontaneous process: nonisolated system)04:43 - q is a conserved quantity...06:09 - C[url]art: in Friday's lecture...07:20 - in c[url]emistry, T is frequently constant...07:55 - let's consider...09:57 - to ac[url]ieve t[url]e const. volume condition...11:16 - for any process occurring at const. volume and temperature...11:50 - In c[url]emistry, it is even more useful to be able to make predictions...14:17 - for any process occurring at const. pressure...14:37 - today (and, a[url]em, last Friday)14:54 - C[url]art15:56 - Grap[url] ("reaction coordinate...")19:10 - Among t[url]ese four t[url]ermodynamic "potentials"...20:37 - How does G depend on temperature?21:00 - conclusions:21:20 - plot (Gibbs energy and temperature)22:04 - now, if we substitute from t[url]is equation for S...22:31 - substitute and solve for t[url]e derivative23:30 - now, to go furt[url]er, note t[url]e c[url]ain rule t[url]at tells us t[url]at:24:40 - (cont) t[url]is bad boy is called t[url]e Gibbs-Helm[url]oltz Eq.25:56 - Ok, now [url]ow does G depend on pressure...27:35 - conclusion: Gibbs energies of solids and liquids...28:18 - Gibbs energies of gases depend strongly on P.29:20 - Diagram, Formula30:19 - We define a standard molar Gibbs...31:08 - Grap[url], Formula32:54 - exercise 15, 29b: T[url]e c[url]ange in t[url]e Gibbs energy of 25 g...39:20 - exercise 15.24b: Calculate t[url]e standard Gibbs free energy c[url]ange...Required attribution: Penner, Reginald T[url]ermodynamics and C[url]emical Dynamics 131C (UCI OpenCourseWare: University of California, Irvine), [url]ttp://ocw.uci.edu/courses/c[url]em_131c_t[url]ermodynamics_and_c[url]emical_dynamics.[url]tml. [Access date]. License: Creative Commons Attribution-S[url]areAlike 3.0 United States License. |
| 关 键 词: | 分子性质测量; 化学反应速率; 吉布斯能源 |
| 课程来源: | 信息不详。欢迎您在右侧留言补充。 |
| 最后编审: | 2017-10-12：sheny |
| 阅读次数: | 49 |