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过冷水中的第二个临界点:事实还是虚构?

Second critical point in supercooled water: Fact or fiction?
课程网址: http://videolectures.net/kolokviji_soper_supercooled_water/  
主讲教师: Alan Soper
开课单位: 科技设施委员会
开课时间: 2016-03-14
课程语种: 英语
中文简介:
水物质的性质继续引起大量的辩论和争议。争议最多的观点是,过冷水有第二个临界点,在该临界点以下,如果存在过冷水,水将相分离为两种不同的液体,即高密度液体和低密度液体。尽管到目前为止还没有直接观察到第二个临界点,但去年[Wang等人,J.Phys.Chem.Lett.62009(2015)]发表的一篇论文声称在多孔二氧化硅基质MCM-41中的水中观察到了这种转变。尽管在这项研究发表之前,有人提出了一些理论和实验上的反对意见,但这一点仍然存在。本次演讲将探讨支持和反对水的第二个临界点方案的论点,并强调进一步的证据,表明该方案可能存在严重缺陷。
课程简介: The nature of water substance continues to attract a large amount of debate and controversy. High on the list of controversies is the idea that supercooled water has a second critical point, below which, if it existed, water would phase separate into two distinct liquids, high density liquid and low density liquid. Although no direct observation of this second critical point has been made to date, a paper last year [Wang et al., J. Phys. Chem. Lett. 6, 2009 (2015)] claimed to have observed this transition in water confined in a porous silica matrix, MCM-41. This was despite several theoretical and experimental objections that had been voiced before this work was published. This talk will look at the arguments for and against the second critical point scenario for water, and highlight yet further evidence that this scenario may have serious flaws.
关 键 词: 水物质的性质; 过冷水; 临界点
课程来源: 视频讲座网
数据采集: 2022-03-28:zkj
最后编审: 2022-03-28:zkj
阅读次数: 36